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[这个贴子最后由eric在 2005/12/18 01:39pm 第 1 次编辑]
1986年第一版国内有两个翻译的版本，广为传阅。2004年kenneth K. Kuo 完成了第二版的第一部分的编写，主要讲述燃烧的化学热力学，动力学，燃烧波，层流预混火焰，层流扩散火焰，以及单液滴燃烧模型等基本内容，偏重理论,2005年出版。第二部分将介绍凝聚相燃烧（包括喷雾燃烧，固体颗粒燃烧等），湍流基础，湍流预混火焰，湍流扩散火焰及单滴燃烧，均相气体和凝聚相物质点火过程，边界层反应流，以及纳米尺度的含能材料燃烧等内容，这部分内容将在第二本书中介绍，书名“turbulent and Two-phase combustion”，尚未出版。
PRINCIPLES OF COMBUSTION 全书750页，复印装订邮寄可能超过200元，如有需要的请报名，并跟我联系：limu_eric@mail.nwpu.edu.cn
qq:35057257
Table of Contents
of
Principles of Combustion
Prepared by
Kenneth K. Kuo
(March 12, 2004)
Preface to the Second Edition
Preface to the First Edition
INTRODUCTION1
Importance of Combustion for Various Applications
Related Constituent Disciplines for Combustion Studies
General Method of Approach to Solving Combustion Problems
General Objectives of Combustion Modeling
Classification of Combustion Problems
General Structure of a Theoretical Model
Governing Equations for Combustion Modeling (Conservation & Transport Equations)
Some Common Assumptions Made In Combustion Models
Several Basic Definitions (Mole Numbers, Mole Fraction, Mass Fraction, Molecular Weight, Density, Concentration, Equation of State, Fuel-Oxidant Ration, Equivalence Ratio, Stoichiometry)
CHAPTER 1.REVIEW OF CHEMICAL THERMODYNAMICS
Nomenclatures
1.Brief Statement of Thermodynamic Laws
2.Equation of State
3.Conservation of Mass
4.The First Law of Thermodynamics; Conservation of Energy
5.The Second Law of Thermodynamics
5.1Equilibrium Thermodynamics
5.2Non-equilibrium Thermodynamics
6.Criteria for Equilibrium
7.Conservation of Atomic Species
8.Various Methods for Reactant-Fraction Specification
8.1Mole and Mass Fractions
8.2Fuel-Oxidant and Fuel-Air Ratios
8.3Equivalence Ratio
8.4Mixture Fraction
9.Standard Enthalpies of Formation
10.Thermochemical Laws
11.Relationship Between Bond Energies and Heats of Formation
12.Heats of Reaction for Constant-Pressure and Constant-Volume Combustion
12.1Constant-Pressure Combustion
12.2Constant-Volume Combustion
13.Energy Balance Considerations for Flame Temperature Calculations
14.Equilibrium Constants
15.Real-Gas Equations of State and Fugacity Calculation
16.More Complicated Dissociation in the Combustion of Hydrocarbons
17.The Clausius-Clapeyron Equation for Phase Equilibrium
18.Calculation of Equilibrium Compositions with NASA';s CEA Computer Program
18.1Assumptions and Capabilities
18.2Equations Describing Chemical Equilibrium
18.2.1 Thermodynamic Equations
18.2.2Minimization of Gibbs Free Energy
19.Other Well-Established Chemical Equilibrium Codes
References
Homework
Projects
CHAPTER 2.CHEMICAL KINETICS AND REACTION MECHANISMS
Additional Symbols
1.Rates of Reactions and Their Functional Dependence
1.1Total Collision Frequency
1.2Equation of Arrhenius
1.3Apparent Activation Energy
1.4Rates of Reaction
1.5 Methods for Measurement of Gas-Phase Reaction Rates
1.5.1 Static Methods
1.5.1.1 Flash Photolysis Resonance Fluorescence Technique
1.5.1.2 Relative Rate Constant Photolysis Technique
1.5.1.3 Laser Photolysis/Laser Induced Fluorescence Technique
1.5.2 Dynamic Methods for Reactions in Flow Systems
1.5.3 Several Methods for Measuring Rapid Reaction Rates
2.One-Step Chemical Reactions of Various Orders
2.1First-Order Reactions
2.2Second-Order Reactions
2.3Third-Order Reactions
3.Consecutive Reactions
4.Competitive Reactions
5.Opposing Reactions
5.1First-Order Reaction Opposed by a First-Order Reaction
5.2First-Order Reaction Opposed by a Second-Order Reaction
5.3Second-Order Reaction Opposed by a Second-Order Reaction
6.Chain Reactions
6.1Free Radicals
6.2Lindemann';s Theory for First-Order Reaction
6.3Complex Reactions
6.3.1 Hydrogen-Bromine Reaction
7.Chain-Branching Explosions
8.CHEMKIN Analysis and Code Application for Gas-Phase Kinetics
8.1Thermodynamic Properties
8.2Reaction Rate Expressions
8.3Brief Description of Procedures in Using CHEMKIN Code
9. Surface Reactions
9.1 Surface Adsorption Processes
9.1.1 The Langmuir Adsorption Isotherm
9.1.2 Adsorption with Dissociation
9.1.3 Competitive Adsorption
9.2 Surface Reaction Processes
9.2.1 Reaction Mechanism
9.2.2 Unimolecular Surface Reactions
9.2.3 Bimolecular Surface Reactions
9.2.4 Desorption
9.3 Kinetic Model of Hydrogen-Oxygen Reaction on Platinum Surface
9.3.1 Simple Kinetic Model of H2/O2 Reaction on Platinum Surface
9.3.2 Kinetic Rates of H2/O2 reaction on Platinum Surface
9.4 Experimental Methods to Study Surface Reactions
9.4.1 Spectroscopic Methods
9.4.1.1 Auger Electron Spectroscopy
9.4.2 Temperature Controlled Methods
9.4.3 Combination of Spectroscopic and Temperature-Controlled Methods
9.5 Surface Reaction Rate Determination
9.5.1 Application of LIF Technique in Surface Reaction Rate Determination
9.5.1.1 The Elementary Steps
9.5.1.2 Experimental Setup
9.5.1.3 Experimental Results
10.Rate Laws for Isothermal Reactions Utilizing Dimensionless Parameters
10.1Equilibrium Constants
10.2Net Rate of Production of Chemical Species
11.Procedure and Applications of Sensitivity Analysis
11.1Introduction to Sensitivity Analysis
11.2The Procedure for Local Sensitivity Analysis
11.2.1 Time-Dependent Zero-Dimensional Problems
11.2.2 The Procedure for Steady-State One-Dimensional Problems
11.2.3 The Procedure for Time-Dependent Spatial Problem
11.3The Example of Sensitivity Analysis of Aliphatic Hydrocarbon Combustion
11.3.1 Local Sensitivity Analysis in One-Dimensional Flame Fronts
11.3.2 Sensitivity Analysis for Zero-Dimensional Problems
12.Reaction Flow Analysis
13.Reaction Mechanisms of H2/O2 Systems
13.1 Background Information about H2/O2 Reaction Systems
13.2 Explosion Limits of H2/O2 Systems
14.Gas-Phase Reaction Mechanisms of Aliphatic Hydrocarbon and Oxygen System
14.1 Specific Mechanisms
14.1.1 Gas-Phase Kinetics of H2 Oxidation
14.1.2 O3 Decomposition Mechanism
14.1.3 CO Oxidation Mechanism
14.1.4 CH2O Reaction
14.1.5 CH4 Oxidation
14.1.6 C2H6 (Ethane) Oxidation
14.1.7 C2H4 (Ethylene) Oxidation
14.1.8 C2H2 (Acetylene) Oxidation
14.1.9 CH2CO (Ketene) Oxidation
14.1.10 CH3OH (Methanol) Reactions
14.1.11 C2H5OH (Ethanol) Reactions
14.1.12 CH3CHO (Acetaldehyde) Reaction
14.2 Discussion of More Complex Cases
15.Reduction of Highly Complex Chemical Kinetic Mechanism to Simpler Reaction Mechanism
15.1 Quasi-Steady State Assumption (QSSA) and Partial Equilibrium Assumption
15.2 Computational Singular Perturbation Methods for Stiff Equations
15.2.1 Stiff Equations
15.2.2 Chemical Kinetic Systems as Stiff Equations
15.2.3 Formulation of the Problem
15.2.4 Procedures for Solving the Chain Reaction Problem
15.3 Some Observations of the CSP Method
16.Formation Mechanism of Nitrogen Oxides
16.1 Thermal NO Mechanism (Zeldovich Mechanism)
16.2 Prompt NO Mechanism (Fenimore Mechanism)
16.3 NO Production from Fuel Bound Nitrogen
16.3.1 The Oxidation of HCN
16.3.2 The NO r HCN r N2 Mechanism
16.3.3 The Oxidation of NH3
16.4 NO2 Mechanism
16.5 N2O Mechanism
16.6 Overall Remarks on NOx Formation
17.Formation and Control of CO and Particulates
17.1 Carbon Monoxide
17.2 Particulate Matters
17.2.1 Major Types of Particulates
17.2.2 Harmful Effects
17.2.3 Particulate Matter Control Methods
References
Homework
CHAPTER 3.CONSERVATION EQUATIONS
FOR MULTICOMPONENT REACTING SYSTEMS
Additional Symbols
1.Definitions of Concentrations, Velocities, and Mass Fluxes
2.Fick';s Law of Diffusion
3.Theory of Ordinary Diffusion in Gases at Low Density
4.Continuity Equation and Species Mass Conservation Equations
5.Conservation of Momentum
5.1Momentum Equation in Terms of Stress
5.1.1 Momentum Equation Derivation By Infinitesimal Particle Approach
5. 1.2 Momentum Equation Derivation By Infinitesimal Control Volume
Approach
5.1.3 Finite Control Volume
5.2Stress-Strain-Rate Relationship (Constitutive Relationship)
5.2.1 Strain Rate
5.2.2 Stress Tensor
5.3Navier-Stokes Equations
6.Conservation of Energy
7.Physical Derivation of the Multicomponent Diffusion Equation
8.Other Necessary Equations in Multicomponent Systems
9.Solution of a Multicomponent-Species System
10.Shvab-Zel';dovich Formulation
11.Dimensionless Ratios of Transport Coefficients
12.Boundary Conditions at an Interface
References
Homework
Projects
CHAPTER 4.DETONATION AND DEFLAGRATION WAVES
OF PREMIXED GASES
Additional Symbols
1.Qualitative Differences between Detonation and Deflagration
2.The Hugoniot Curve
3.Properties of the Hugoniot Curve
3.1Entropy Distribution along the Hugoniot Curve
3.2Comparison of the Burned-Gas Velocity Behind a
Detonation Wave with the Local Speed of Sound
4.Determination of Chapman-Jouguet Detonation-Wave Velocity
4.1Trial-and-Error Method
4.2The Newton-Raphson Iteration Method
4.3Comparison of Calculated Detonation-Wave Velocities
with Experimental Data
5.Detonation-Wave Structure
5.1ZND One-Dimensional Wave Structure
5.2Multidimensional Detonation-Wave Structure
5.3Numerical Simulation of Detonations
6. The Mechanism of Deflagration-to-Detonation Transition (DDT)
in Gaseous Mixtures
7. Detonability and Chemical Kinetics: Limits of Detonability
7.1Classical Model of Belles
7.2 Detonability Limits of Confined Fuel Mixtures
7.2.1 Initial Condition Dependence
7.2.2 Boundary Condition Dependence
7.2.3 Single-Head Spin Detonation
7.3Detonability Criteria and Detonation Cell Size
7.4Chemical Kinetics of Detonation in H2-Air-Diluent Mixtures
8. Non-Ideal Detonations
8.1Definition of Non-ideal Detonation and Zel';dovich and Shchelkin';s Detonation Mechanisms in Rough Tubes
8.2Theoretical Considerations of Energy and Momentum Losses
8.3Critical Pipe Diameter Consideration
8.4Effect of Several Physical and Chemical Parameters on detonability
8.5 Possible Measures for Reducing Potential of Detonation Wave Generation
9. Consideration of Spontaneous Detonation Initiation
9.1 Functional Form of Distribution of Ignition Delay
9.2 Experimental Verification of Processes of Non-Explosive Detonation Initiation
9.2.1 Photochemical Initiation of Detonation in Mixtures with Non-Uniform
Concentration
9.2.2 Gasdynamic Jet as a Method of Creating Temperature-Concentration Non-
Uniformity
9.3 General Observation and Status of Understanding
References
Homework
Project
CHAPTER 5.PREMIXED LAMINAR FLAMES
Additional Symbols
1.Introduction and Flame Speed Measurement Methods
1.1 Bunsen Burner Method
1.2 Constant-Volume Spherical Bomb Method
1.3 Soap-Bubble (Constant-Pressure Bomb) Method
1.4 Particle-Track Method
1.5 Flat-Flame Burner Method
1.6Diagnostic Method for Flame Structure Measurements
1.6.1 Velocity Measurements
1.6.2 Density Measurements
1.6.3 Concentration Measurements
1.6.3 Tempetature Measurements
2.Classical Laminar Flame Theories
2.1Thermal Theory: Mallard and LeChatelier';s Development
2.2 Comprehensive Theory: The Theory of Zel';dovich, Frank-Kamenetsky and
Semenov
2.3Diffusion Theory: The Theory of Tanford and Pease
3. Contemporary Method for Solving Laminar Flame Problems
3.1 Premixed O3/O2 Laminar Flames
3.2 CHEMKIN Code for Solving Premixed Laminar Flame Structures
4.Dynamic Analysis of Stretched Laminar Premix Flames
4.1Definition of Flame Stretch Factor and Karlovitz Number
4.2 Balance Equation for Premixed Laminar Flame Area
4.3 The Use of Expanding Spherical Flames to Determine Burning Velocities and Stretch Effects in Hydrogen/Air Mixtures
4.4 Laminar Burning Velocities and Markstein Numbers of
Hydrocarbon/Air Flames
4.5Burning Rates of Ultra-Lean to Moderately-Rich H2/O2/N2 Laminar Flames with Pressure Variations
5.Effect of Chemical and Physical Variables on Flame Speed
5.1 Chemical Variables
5.1.1 Effect of Mixture Ratio
5.1.2 Effect of Fuel Molecular Structure
5.1.3 Effects of Additives
5.2 Physical Variables
5.2.1 Effect of Pressure
5.2.2 Effect of Initial Temperature
5.2.3 Effect of Flame Temperature
5.2.4 Effect of Thermal Diffusivity and Specific Heat
6.Principle of Stabilization of Combustion Waves in Laminar Streams
7.Flame Quenching
8.Flammability Limits of Premixed Laminar Flames
8.1Flammability Limits Determined from a Standard Glass Tube
8.2Effect of Pressure and Temperature on Flammability Limit
8.3Spalding';s Theory of Flammability Limits and Flame Quenching
8.4Flame Structure Near the Flammability Limits of Premixed Hydrogen-Oxygen Flames
References
Homework
Projects
CHAPTER 6.GASEOUS DIFFUSION FLAMES AND COMBUSTION OF A SINGLE LIQUID FUEL DROPLET
1.Burke and Schumann';s Theory of Laminar Diffusion Flames
1.1Basic Assumptions and Solution Method
1.2Flame Shape and Flame Height
2.Phenomenological Analysis of Fuel Jets
3.Laminar Diffusion Flame Jets
3.1Laminar Jet Mixing
3.2Laminar Jet with Chemical Reactions
3.3 Numerical Solution of Two Dimensional Axisymmetric Laminar Diffusion Flames
3.4 Effect of Preferential Diffusion of Species and Heat in Laminar Diffusion
Flames
4. Evaporation and Burning of a Single Droplet in a Quiescent Atmosphere
4.1 Evaporation of a Single Fuel Droplet
4.2Mass Burning Rate of a Single Fuel Droplet
5. Fuel Droplet in a Convective Stream
5.1 Correlation Development for Nearly Spherical Droplets in Convective Streams
5.2 Simulation of Deformed Droplets Dynamics
5.3 Effect of Internal Circulation on Droplet Vaporization Rate
6. Supercritical Burning of Liquid Droplets in a Stagnant Environment
6.1 Thermodynamic and Transport Properties
6.1.1 Extended Corresponding-State Principle
6.1.2 Equation of State
6.1.3 Thermodynamic Properties
6.1.4 Transport Properties
6.2 Vapor-Liquid Phase Equilibrium
6.3 Droplet Vaporization in Quiescent Environments
6.4 Droplet Combustion in Quiescent Environments
6.5 Droplet Vaporization in Supercritical Convective Environments
6.6 Droplet Response to Ambient Flow Oscillation
References
Homework
Projects
Appendix A: Evaluation of Thermal and Transport Properties of Gases and Liquids
Appendix B: Constants and Conversion Factors Often Used in Combustion
Appendix C: Naming of Hydrocarbons
Appendix D: Melting, Boiling, and Critical Temperatures of Elements
Appendix E: Periodic Table and Electronic Configurations of Neutral Atoms in Ground States
Author Index
Subject Index
About the Author................................................................................................
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